I edited your config a little.
I removed all the false nodes at the default level. As i said earlier, permissions are always false unless you...
Why you would deny all permissions first? PermissionsBukkit already works with a 'deny by default' policy. If you don't give a 'true' permission...
Don't use tabs. Tabs don't work.
Always indent everything with spaces.
The permission nodes for the armageddon plugin where not correctly indented. They needed to be 4 spaces further. Also i removed 2 empty lines. one...
Try manually adding the first user like this:
# PermissionsBukkit configuration file
# A permission node is a string like 'permissions.build',...
Try removing the empty lines just above and below 'users:'.
It definitely matters where you put the config file yes. It should be in you 'server => plugins => permissionsbukkit' folder.
Remove any empty lines. The plugin doesn't seem to like empty lines. xD
Also make sure that you don't use tabs for indention. Only spaces.
If you give the 'iZone.*: true' permission to the 'default' group, everyone should be able to use all the izone permissions.
You could also...
The 'iZone.*: true' node automatically sets all the iZone permissions to 'true' for the group.
I don't know. The only thing i would say is to delete the empty line at the top of your PermissionsBukkit config. But if all other permissions...
Exactly like that yes. :P
Honestly... i don't know.
The way i do it, is that i'm not even an OP on my own server. I handle everything with permissions. As...
There are still a lot of permission nodes with tabs BEHIND them though. Try removing those too.
Oh, wait. Now i see.
You have some nodes with tabs behind the nodes.
Check the nodes and remove the tabs that are behind the nodes.
Separate names with a comma.